Concepedia

Bis(trifluoromethyl)trioxide: First Structure of a Straight‐Chain Trioxide

Karina I. Gobbato, Heinz Oberhammer, Martin Frank Klapdor, Dietrich Mootz, Wolfgang Poll, Sonia E. Ulic, Helge Willner

Angewandte Chemie International Edition in English · 1995 · 17 citations · 14 references

DOI

Abstract

A skew structure with trans orientation of the two CF3 groups and with an OOOC dihedral angle of 96° describes the trioxide CF3OOOCF3 (see picture). The OO bond lengths are 1.452(5) (gas phase) and 1.437(2) Å (crystal).

References

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Phase annealing in SHELX-90: direct methods for larger structures

George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 1990 · 16.3K citations

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On the geometry and internal rotation of XSCF3 compounds (X = F, Cl and CF3)

Heinz Oberhammer, W. Gombler, Helge Willner · Journal of Molecular Structure · 1981 · 233 citations

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On the r structure and the torsional potential function of hydrogen peroxide

Jacek Koput · Journal of Molecular Spectroscopy · 1986 · 124 citations

Recent results in solid state chemistry of ionic ozonides, hyperoxides, and peroxides

Werner Hesse, Martin Jansen, Wolfgang Schnick · Progress in Solid State Chemistry · 1989 · 79 citations

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Reaction of oxygen difluoride. Addition to carbonyl fluoride to produce bis(trifluoromethyl) trioxide

L. R. Anderson, W. B. FOX · Journal of the American Chemical Society · 1967 · 73 citations

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