Journal of the Chemical Society Perkin Transactions 2 · 1995 · 18 citations · 1 references
Natural SciencesChemistryChemical KineticsOrganic ChemistryPhysical ChemistryAddition ReactionsNitrogen OxidesNitrogen Oxides ChemistryRadical ReactionsReaction MechanismsAddition MechanismsNitrogen DioxideNitrogen Oxide Radical ChemistryNitrogen Oxide Reaction MechanismsReactive Electrophile Species
In spite of the observation of 15N nuclear polarisation expected from the separate addition of two NO2˙ radicals in the reaction of nitrogen dioxide with allylbenzene and some other alkenes, kinetic studies indicate that both NO2˙ and N2O4 are reactive species, each leading only to addition products.
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