Concepedia

Synthesis and crystal structure of [Mn<sup>II</sup>(H<sub>3</sub>L)(L)Mn<sup>IV</sup>][PF<sub>6</sub>]<sub>3</sub>[H<sub>3</sub>L =N,N′,N″-tris-(2S)-2-hydroxypropyl-1,4,7-triazacyclononane]: a mixed-valence pendant-arm macrocycle dimer in which the ligand adopts different angular geometries at the two metal centres

Arafa Belal, Ian A. Fallis, Louis J. Farrugia, Norman M. Macdonald, Robert D. Peacock

Journal of the Chemical Society Chemical Communications · 1991 · 13 citations · 5 references

DOI

Concepts

Abstract

Reaction of N,N′,N″-tris-(2S)-2-hydroxypropyl-1,4,7-triazacyclononane (H3L) with MnCl2 in neutral or slightly basic conditions affords (MnII(H3L)(L)MnIV][PF6]3, a mixed-valence, hydrogen-bridged dimer in which the MnIV half has pseudooctahedral geometry and the MnII half has trigonal prismatic geometry.

References

5

Complexes of polyaza macrocycles bearing pendent coordinating groups

Paul V. Bernhardt, Geoffrey A. Lawrance · Coordination Chemistry Reviews · 1990 · 331 citations

, , +12

1,4,7-Triazacyclononane-N,N',N''-triacetate (TCTA), a new hexadentate ligand for divalent and trivalent metal ions. Crystal structures of [CrIII(TCTA)], [FeIII(TCTA)], and Na[CuII(TCTA)].bul.2NaBr.bul.8H2O

Karl Wieghardt, Ursula Bossek, Phalguni Chaudhuri et al. · Inorganic Chemistry · 1982 · 149 citations

, , +9

Synthesis and coordination chemistry of the hexadentate ligands 1,4,7-tris(2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L1) and 1,4,7-tris(3-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L2). Crystal structures of [HL1CuII] and [L2FeIII]acacH

Ulf Auerbach, Uwe Eckert, Karl Wieghardt et al. · Inorganic Chemistry · 1990 · 84 citations

, , +9

Synthesis of a Tetranuclear Manganese(<scp>IV</scp>) Cluster with Adamantane Skeleton: [(C<sub>6</sub>H<sub>15</sub>N<sub>3</sub>)<sub>4</sub>Mn<sub>4</sub>O<sub>6</sub>]<sup>4+</sup>

Karl Wieghardt, Ursula Bossek, W. Gebert · Angewandte Chemie International Edition in English · 1983 · 81 citations

, , +14

Synthesis and spectroscopic studies of cobalt(<scp>III</scp>) complexes of the chiral pendant-arm macrocycle N,N′,N″-tris[(2S)-2-hydroxypropyl]-1,4,7-triazacyclononane (H<sub>3</sub>L); crystal structure of the hydrogen-bridged dimer [CoLH<sub>3</sub>LCo][PF<sub>6</sub>]<sub>3</sub>

Arafa Belal, Louis J. Farrugia, Robert D. Peacock et al. · Journal of the Chemical Society Dalton Transactions · 1989 · 27 citations

, , +13