Formation of a Special Intermediate during Phase Transformation of Zeolite NaA to Nepheline

Abstract

Abstract In the process of phase transformation of zeolite NaA to nepheline under hydrothermal conditions a special intermediate occurs. This is due to the high reaction rate of nepheline formation in the presence of water molecules. Consequently, the usually observed amorphous material with high condensed silica does not occur as separate phase. – The intermediate which is formed due to the destruction of the long‐range order of zeolite is significantly short‐range ordered. The phase transformation process starts at the outer surface of zeolite crystals, thus generating a diffusion barrier for sorption uptake processes.