Light-assisted deep-trapping of holes in conjugated polymers

Josh C. Bolinger, Leonid Fradkin, Kwang-Jik Lee, Rodrigo E. Palacios, Paul F. Barbara

Proceedings of the National Academy of Sciences · 2009 · 29 citations · 37 references

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Abstract

The injection of positive charge carriers (holes) into a single conjugated polymer chain was observed to be light-assisted. This effect may underlie critical, poorly understood organic electronic device phenomena such as the build-up of functional deeply trapped charge layers in polymer light emitting diodes. The charging/discharging dynamics were investigated indirectly by a variety of single molecule electro-optical spectroscopic techniques, including an "image-capture" approach.

References

37