Langmuir–Blodgett Films of Single-Wall Carbon Nanotubes: Layer-by-layer Deposition and In-plane Orientation of Tubes

Abstract

The Langmuir–Blodgett technique has been applied to build optically homogeneous thin films of chemically solubilized single-wall carbon nanotubes (s-SWNTs) which possess good surface spreading properties at the air/water interface. Deposition can be performed in a layer-by-layer fashion up to 100 or more layers either by horizontal lifting or vertical dipping, allowing to readily control the film thickness. Their visible to near-infrared absorption spectra showing the characteristic features of semiconducting and metallic SWNTs prove the intactness of their one-dimensional electronic states during the preparation process. Polarized absorption spectroscopy and atomic force microscope (AFM) observation demonstrate that the tubes are oriented in the direction of the trough barrier (horizontal lifting) or in the dipping direction (vertical dipping). These are attributed to compression-induced or flow-induced orientation, respectively, the latter found to be much stronger than the former. The realization of homogeneous thin films of SWNTs with a controllable thickness and tube orientation should be an important basis for the future development of their scientific understanding and technological applications.