Concepedia

Benzotriazole-Mediated Selective Chromium(VI) Oxidations

Edward J. Parish, Sarawanee Chitrakorn

Synthetic Communications · 1985 · 30 citations · 14 references

DOI

Concepts

Abstract

Abstract Complexation of chromium trioxide with benzotriazole has been found to be an effective reagent for allylic oxidation. Pyridinium chlorochromate complexed with benzotriazole was found to selectively oxidize steroidal allylic alchols in high yield.

References

14

Active Manganese Dioxide Oxidation in Organic Chemistry - Part I

Alexander J. Fatiadi · Synthesis · 1976 · 320 citations

, , +13

Allylic oxidation with 3,5-dimethylpyrazole. Chromium trioxide complex steroidal .DELTA.5-7-ketones

William G. Salmond, M. A. BARTA, Jeffrey L. Havens · The Journal of Organic Chemistry · 1978 · 281 citations

, , +6

Allylic oxidation of olefins with chromium trioxide pyridine complex

William G. Dauben, Milton E. Lorber, Dwight S. Fullerton · The Journal of Organic Chemistry · 1969 · 230 citations

, , +5

4-(Dimethylamino)pyridinium chlorochromate, a new selective reagent for the oxidation of allylic and benzylic alcohols

Frank S. Guziec, Frederick A. Luzzio · The Journal of Organic Chemistry · 1982 · 77 citations

, , +4

A new reagent for the selective oxidation of steroidal allylic alcohols to αβ-unsaturated ketones

David J. Burn, V. Petrow, Georgie Weston · Tetrahedron Letters · 1960 · 67 citations

, , +5