Publication | Closed Access
Iridium‐Catalyzed H/D Exchange
44
Citations
11
References
2005
Year
EngineeringOrganometallic ElectrochemistryOrganic ChemistryChemistryChemical EngineeringH/d ExchangeIridium‐catalyzed H/d ExchangeOrganometallic CatalysisRedox ChemistryHomogeneous CatalysisInorganic ChemistryCatalysisHydrogenQuantum ChemistryMolecular ChemistryGeneral MechanismNatural SciencesHeterogeneous CatalysisD 2Molecular Catalysis
Abstract The scope and limitation of an iridium‐catalysed H/D exchange reaction has been investigated. Our results suggest a general mechanism for specific labelling at aromatic and non‐aromatic double bonds by D 2 O if an electron‐donating group is in a 1,4‐relation with the carbon where the H/D exchange takes place. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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