Physical properties of polymer electrolytes: nuclear magnetic resonance investigation and comparison with

Abstract

The physical properties of the ionic conductor [Formula: see text], obtained by dissolution of lithium trifluoromethanesulphonylimide in poly(propylene oxide), have been investigated for several values of n. The glass transition temperature [Formula: see text] has been established from both DSC and NMR techniques. The diffusion coefficients of [Formula: see text]-containing species have been determined by the pulsed magnetic field gradient technique. The behaviour of the proton relaxation time [Formula: see text] versus temperature and concentration has been correlated to the glass temperature. The behaviour of the proton transverse relaxation function, obtained by the spin-echo technique, has been interpreted using a simple model in which two regimes and consequently two transverse relaxation times coexist and are assigned to the `entangled' and `non-entangled' parts of the high-molecular-weight polymer chains investigated.