Redox-Switching of Nonlinear Optical Behavior in Langmuir−Blodgett Thin Films Containing a Ruthenium(II) Ammine Complex

Leïla Boubekeur‐Lecaque, Benjamin J. Coe, Koen Clays, Stijn Foerier, Thierry Verbiest, Inge Asselberghs

Journal of the American Chemical Society · 2008 · 139 citations · 11 references

Concepts

Abstract

Alternating Langmuir−Blodgett multilayers containing a metal-to-ligand charge-transfer chromophore based on {Ru II (NH 3 ) 5 } 2+ show redox-switching of the second harmonic generation from a 1064 nm laser.

References

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