Angewandte Chemie International Edition · 2000 · 44 citations · 0 references
Natural SciencesBiochemistryChemistryCarbohydrate ChemistryStructural BiochemistryStructural BiologyCoordination ChemistryLigand BindingLigand-based DesignMagnetism Of Inorganic CompoundsMetal-ligand BondingTransition Metal ComplexesBioinorganic Coordination ChemistryCatechol OxidaseComplexation ChemistryMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesMetalloid ComplexesSupramolecular Coordination Complexes
Remarkably high magnetic coupling and O(2)-activation ability analogous to that of catechol oxidase are characteristics of the first structurally defined, low-symmetry oligonuclear copper complexes of tridentate beta-oxoenamine ligands based on amino carbohydrates (the structure of a bis(acetylbutenonylaminoglucosidato)bis(µ-acetato)tricopper(II) complex is shown).