P‐Stereogenic Optically Active Polymer and the Complexation Behavior

Abstract

Abstract The synthetic details of the P‐stereogenic optically active polymer and the complexation behavior with palladium and platinum complexes are reported. The polymer consists of P‐stereogenic bisphosphine units and the conjugated phenylene‐ethynylene units alternately. The P‐stereogenic bisphosphine moieties can coordinate to transition metals such as palladium and platinum, leading to a change in the conformation.