Publication | Closed Access
Catalytic Asymmetric Dearomatizing Redox Cross Coupling of Ketones with Aryl Hydrazines Giving 1,4-Diketones
103
Citations
53
References
2015
Year
Chemical EngineeringCross-coupling ReactionEngineeringAll-carbon Quarternary StereocenterOrganic ChemistryRedox CrossOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisEnantioselective SynthesisAsymmetric Brønsted Acid
An asymmetric Brønsted acid catalyzed dearomatizing redox cross coupling reaction has been realized, in which aryl hydrazines react with ketones to deliver 1,4-diketones, bearing an all-carbon quarternary stereocenter in high enantiopurity.
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