Concepedia

A mixed valence binuclear complex of vanadium(<scp>IV</scp>) and vanadium(<scp>V</scp>). X-Ray crystal structure of (NH<sub>4</sub>)<sub>3</sub>[V<sub>2</sub>O<sub>3</sub>(nitrotriacetate)<sub>2</sub>]·3H<sub>2</sub>O

Masato Nishizawa, Ken Hirotsu, Shun’ichiro Ooi, Kazuo Saito

Journal of the Chemical Society Chemical Communications · 1979 · 65 citations · 0 references

DOI

Concepts

Abstract

A deep blue mixed valence complex [VO(nta)–O–VO(nta)]3–(nta = nitrilotriacetate) was found to be in equilibrium with [VIVO(nta)(H2O)]– and [VVO2(nta)]2– in aqueous solution; the crystal structure of its ammonium salt trihydrate has been determined.