Carbon-supported Pt–Ru nanoparticles prepared in glyoxylate-reduction system promoting precursor–support interaction

Abstract

A high dispersion of carbon-supported Pt–Ru alloy nanoparticles have been prepared in an alkaline aqueous solution by using glyoxylate as a reducing agent. The glyoxylate monoanion is converted to oxalate dianion with the reduction of metal precursor ions. The surface-potential analysis of unsupported Pt–Ru black in the presence of all the anion species coexistent in the preparation system suggests a possibility of oxalate dianion as the most effective particle stabilizer. In the glyoxylate-reduction system, a precursor–support interaction is significantly promoted to affect the formation and stabilization of nanoparticles. The glyoxylate reduction at 20-wt% metal loading has provided a higher Pt(0)/Ru concentration ratio in the near-surface region than that of 60-wt% catalyst. The structural and morphological features and advantageous surface composition of the 20-wt% catalyst contribute to the high mass activity for methanol oxidation in the anode overpotential range of typical direct methanol fuel cells.