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Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus–arsenic and phosphorus–antimony double bonds
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1983
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HalogenationInorganic ChemistryChemical EngineeringEngineeringHeterocyclicPhosphorus–antimony Double BondsDouble-bonded CompoundsChemistryHeterocycle ChemistryPharmacologySynthetic ChemistryInorganic SynthesisInorganic Compound
The reaction of (Me3Si)2CHMCl2(M = As or Sb) with (2,4,6-But3C6H2)PH2 in the presence of 1,5-diazabicyclo[5.4.0]undec-5-ene affords the double-bonded compounds, (2,4,6-But3C6H2)PMCH(SiMe3)2(M = As or Sb)