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Radical addition to vinyl phosphonates. A new synthesis of isosteric phosphonates and phosphonate analogues of α-amino acids
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1989
Year
Radical AdditionBioorganic ChemistryEngineeringOrganic ChemistryChemistryChemical DerivativeSide Chain α-Amino-acidsBiosynthesisPhosphonate AnaloguesDiethylvinyl PhosphonateStereoselective SynthesisDerivativesBiochemistryIsosteric PhosphonatesDiversity-oriented SynthesisOligonucleotidePhosphonic AnaloguesBiomolecular EngineeringNatural SciencesDerivative (Chemistry)Synthetic Chemistry
Derivatives of the phosphonic analogues of nucleotides and of side chain α-amino-acids can be readily prepared by irradiation of acyl-N-hydroxy-2-thiopyridones in the presence of diethylvinyl phosphonate.