Publication | Closed Access
Palladium‐Catalyzed Arylation of Tetrasubstituted Double Bonds: A Simple Synthesis of Annelated Propellanes
67
Citations
10
References
1993
Year
Cross-coupling ReactionEngineeringAlkene MetathesisStrained Double BondsSimple SynthesisOrganic ChemistryAnnelated PropellanesPalladium-catalyzed Annelation ReactionsCatalysisOrganometallic CatalysisChemistrySymmetric Propellane 1Tetrasubstituted DoubleAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Only two steps are required for the synthesis of the symmetric propellane 1 starting from acenaphthylene. In this conversion the reactivity of strained double bonds is used for palladium-catalyzed annelation reactions.
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