Physical Review Letters · 1994 · 320 citations · 21 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsCrystal StructureSurface ScienceAtomistic ModelingNucleationSurface DiffusionSurface MorphologySurface PhysicsThin Film NucleationAdatom DiffusionCoalescenceCoverageCoverage Dependence Of Surface DiffusionDeposition RateEpitaxial Growth KineticsIsland GrowthSurface Diffusion Kinetics
The aggregation of adatoms into 2D islands is studied as a function of coverage FTHETA and the ratio of surface diffusion rate to deposition rate gerR=D/F by Monte Carlo simulations of a model of epitaxial growth that permits atoms to detach from island edges at a rate determined by a pair bond energy ${\mathit{E}}_{\mathit{N}}$. The total island density is observed to saturate before coalescence becomes important. In this regime, the density of adatoms ${\mathit{N}}_{1}$\ensuremath{\sim}${\mathit{FTHETA}}^{\mathrm{\ensuremath{-}}\mathit{r}}$${\mathit{gerR}}^{\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\omega}}}$ while the density of islands composed of s>1 atoms ${\mathit{N}}_{\mathit{s}}$\ensuremath{\sim}FTHETA〈s${\mathrm{〉}}^{\mathrm{\ensuremath{-}}2}$g(s/〈s〉) where the average island size 〈s〉\ensuremath{\sim}${\mathit{FTHETAgerR}}^{\mathit{x}}$. The exponents r, \ensuremath{\omega}, and \ensuremath{\chi} vary smoothly with ${\mathit{E}}_{\mathit{N}}$.
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