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Novel Tetrathiafulvalenes Based on Macrocyclic Thioethers
11
Citations
8
References
1996
Year
EngineeringTetrathiafulvalenes 11Natural SciencesDiversity-oriented SynthesisKey Compound 4,5‐BisAbstract Macrocyclic PolythioethersOrganic ChemistryChemistryHeterocycle ChemistryNovel TetrathiafulvalenesSynthetic ChemistryBiomolecular EngineeringPolymers
Abstract Macrocyclic polythioethers ( 7 – 10 , 17 ) and the oxothioether 21 were synthesized by starting with the key compound 4,5‐bis(benzoylthio)‐1,3‐dithiole‐2‐thione ( 1 ). Intramolecular phosphite coupling reactions yielded symmetrically and unsymmetrically substituted tetrathiafulvalenes 11 – 14 and 22 , respectively.
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