Publication | Closed Access
Structure of an η<sup>1</sup> Nickel <i>O</i>-Enolate: Mechanistic Implications in Catalytic Enyne Cyclizations
91
Citations
36
References
2001
Year
Inorganic ChemistryAlkynyl EnalEngineeringOxidative CyclizationHeterocyclicCatalytic Enyne CyclizationsOrganometallic CatalysisCatalysisMetallacyclic FrameworkChemistryEnantioselective SynthesisBiomolecular EngineeringMechanistic Implications
Two metallacycles derived from the oxidative cyclization of nickel(0) with an alkynyl enal have been isolated and fully characterized. The metallacycles obtained possess an η1 nickel O-enolate motif within the metallacyclic framework.
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