Concepedia

TEMPO: a novel chameleonic ligand for s-block metal amide chemistry

G.C. Forbes, Alan R. Kennedy, Robert E. Mulvey, P.J.A. Rodger

Chemical Communications · 2001 · 74 citations · 6 references

DOI

Concepts

Abstract

The first structurally characterised examples of the nitroxide TEMPO acting as a ligand towards Li, Na or Mg are described, through a series of hexamethyldisilazide complexes which reveals a remarkable breadth of variety in structure and in the mode of ligation.

References

6

Interaction of spin labels with transition metals

Sandra S. Eaton, Gareth R. Eaton · Coordination Chemistry Reviews · 1978 · 154 citations

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Highly Hindered Amido-Lithium and Amido-Magnesium Complexes. Crystal-Structures of [Li(Mu-N(SiMe3)2)(Tetrahydrofuran)]2 and [MgBus(Mu-N(SiMe3)2)]2

LM Engelhardt, B. S. JOLLY, CL Raston et al. · Australian Journal of Chemistry · 1986 · 127 citations

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Macromolecular engineering via 'living' free radical polymerizations

Eva Malmström, Craig J. Hawker · Macromolecular Chemistry and Physics · 1998 · 119 citations

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Structural and redox properties of the Tempo adducts of copper(II) halides

J Laugier, Jean Marc Latour, Andréa Caneschi et al. · Inorganic Chemistry · 1991 · 68 citations

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Trapping of free alkyl radical intermediates in the reaction of alkyl bromdies with magnesium

Lynnette M. Lawrence, George M. Whitesides · Journal of the American Chemical Society · 1980 · 51 citations

, , +7