Publication | Closed Access
Transition Metals Complexed to Ordered Mesophases: Palladium-Azo Complexes
74
Citations
5
References
1982
Year
Materials ScienceInorganic ChemistryEngineeringCoordination ComplexRelated Free LigandsTransition Metals ComplexedMolecular ComplexChemistryNew Organometallic CompoundsK-n Phase TransitionCrystallographyInorganic SynthesisInorganic Compound
Abstract The synthesis and characterization of palladium (II) complexes with liquid crystal azobenzene ligands is reported. The new organometallic compounds, having a [sgrave] metal-carbon bond and a metal-metal chloro bridge, display ordered mesophases. The temperatures of the K-N phase transition, in the region of 200°C, are some 130° higher than those for the related free ligands.
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