Concepedia

Transition Metals Complexed to Ordered Mesophases: Palladium-Azo Complexes

Mauro Ghedini, Marcello Longeri, Roberto Bartolino

Molecular crystals and liquid crystals · 1982 · 74 citations · 5 references

DOI

Concepts

Abstract

Abstract The synthesis and characterization of palladium (II) complexes with liquid crystal azobenzene ligands is reported. The new organometallic compounds, having a [sgrave] metal-carbon bond and a metal-metal chloro bridge, display ordered mesophases. The temperatures of the K-N phase transition, in the region of 200°C, are some 130° higher than those for the related free ligands.

References

5

Formation of Covalent Bonds from Platinum or Palladium to Carbon by Direct Substitution

Arthur C. Cope, Robert W. Siekman · Journal of the American Chemical Society · 1965 · 436 citations

, , +10

Cyclopalladation reaction

Swiatoslav Trofimenko · Inorganic Chemistry · 1973 · 192 citations

, , +5

Mesomorphic Transition Metal Complexes. 4. Dithiene Complexes of Ni, Pd, and Pt.

Ulrich T. Mueller‐Westerhoff, A. I. Nazzal, Robert J. Cox et al. · Molecular crystals and liquid crystals · 1980 · 78 citations

, , +10

Vibrational spectra of the chloro- and bromo-π-allylpalladium dimers and of the π-2-methylallyl analogues

David M. Adams, A. Squire · Journal of the Chemical Society A Inorganic Physical Theoretical · 1970 · 33 citations

, , +17

Synthesis and Thermal Properties of a Possibly Mesomorphic Palladium Chelate

Bernard J. Bulkin, R. K. Rose, A. Santoro · Molecular crystals and liquid crystals · 1977 · 21 citations

, , +8