Concepedia

The reduction of (µ<sub>2</sub>-NO) in [HRu<sub>3</sub>(CO)<sub>10</sub>(µ<sub>2</sub>-NO)] to (µ<sub>3</sub>-NH) and (µ<sub>2</sub>-NH<sub>2</sub>) by molecular hydrogen

Brian F. G. Johnson, Jack Lewis, Julian M. Mace

Journal of the Chemical Society Chemical Communications · 1984 · 14 citations · 0 references

DOI

Concepts

Abstract

[HRu3(CO)11]– reacts with NOBF4 in moist MeCN to generate HRu3(CO)10NO, HRu3(CO)10NH2, and HRu4N(CO)12; the same products, together with H2Ru3(CO)9NH and H4Ru4(CO)12, are observed in the direct hydrogenation of HRu3(CO)10NO.