The Journal of Chemical Physics · 1984 · 62 citations · 26 references
Natural SciencesChemical EngineeringChemistryMultiphase FlowPhysical ChemistryTransport PhenomenaMixing ThermodynamicsMixture ThermodynamicsPhase EquilibriaCoexistence CurveCritical ConcentrationCritical TemperaturePhase Separation MechanismsTemperature Effects On Phase BehaviorVolume Fraction Effects
Measurements on the coexistence curves of the binary fluid mixture methanol–cyclohexane with increasing amounts of acetone impurity showed essentially linear changes in the critical temperature and critical concentration with impurity. Adding 1.0% acetone impurity caused the critical temperature to decrease by 3.4 K, the effective critical exponent β to increase and the critical concentration, as measured by volume fraction methanol, to decrease by 0.005.
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John W. Cahn · The Journal of Chemical Physics · 1977 · 1.9K citations
Natural Sciences, Materials Science, Condensed Matter Physics +16
Problems in Physics with many Scales of Length
Kenneth G. Wilson · Scientific American · 1979 · 566 citations
An Interface Phase Transition: Complete to Partial Wetting
Michael R. Moldover, John W. Cahn · Science · 1980 · 309 citations