Concepedia

Structure and magnetism of the ladder-like coordination polymer Co<sub>3</sub>(dca)<sub>2</sub>(nic)<sub>4</sub>(H<sub>2</sub>O)<sub>8</sub>·2H<sub>2</sub>O [dca = dicyanamide anion, N(CN)<sub>2</sub><sup>−</sup>; nic = nicotinate anion]

A.M. Kutasi, Stuart R. Batten, Alexander R. Harris, Boujemaa Moubaraki, Keith S. Murray

CrystEngComm · 2002 · 20 citations · 25 references

DOI

Concepts

Abstract

The structure of the title complex has ladder-like 1D nets containing bridging μ-dca anions and both bridging and terminal nic anions; no long-range magnetic ordering is observed.

References

25

Hard magnets based on transition metal complexes with the dicyanamide anion, {N(CN)2}-,

Mohamedally Kurmoo, Cameron J. Kepert · New Journal of Chemistry · 1998 · 333 citations

, , +17

Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2−

Stuart R. Batten, Richard Robson, Stuart R. Batten et al. · Chemical Communications · 1998 · 310 citations

, , +16

Structure and Magnetic Ordering of M<sup>II</sup>[N(CN)<sub>2</sub>]<sub>2</sub> (M = Co, Ni)

Jamie L. Manson, Carmen R. Kmety, Q. Huang et al. · Chemistry of Materials · 1998 · 305 citations

, , +16

Syntheses, structures and magnetism of α-Mn(dca)2, [Mn(dca)2(H2O)2]·H2O, [Mn(dca)2(C2H5OH)2]·(CH3)2CO, [Fe(dca)2(CH3OH)2] and [Mn(dca)2(L)2], where L = pyridine, CH3OH or DMF and dca− = dicyanamide, N(CN)2− †

Stuart R. Batten, Paul R. Jensen, Cameron J. Kepert et al. · Journal of the Chemical Society Dalton Transactions · 1999 · 187 citations

, , +17

Spontaneous Magnetization in the M[N(CN)<sub>2</sub>]<sub>2</sub> (M = Cr, Mn) Weak Ferromagnets

Jamie L. Manson, Carmen R. Kmety, Arthur J. Epstein et al. · Inorganic Chemistry · 1999 · 181 citations

, , +14