The titanium(IV) complex of a hexadentate tricatechol ligand: synthesis, crystal structure and electrochemistry

F. Ekkehardt Hahn, Stefan Rupprecht, Klaus H. Moock

Journal of the Chemical Society Chemical Communications · 1991 · 29 citations · 5 references

Concepts

Abstract

The tricatechol ligand, tripace, forms an octahedral complex with TiIV; the complex possesses a protonated central nitrogen atom in the ‘in’ conformation and is stable towards reduction up to E1/2=–1.02 V vs. standard calomel electrode.

References

5