Concepedia

Monomeric bis(η<sup>2</sup>-alkyne) complexes of (η<sup>1</sup>-mesityl)copper(<scp>I</scp>) and (η<sup>1</sup>-mesityl)silver(<scp>I</scp>) obtained from a bis(alkynyl)titanocene; X-ray structure of [(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>SiMe<sub>3</sub>)<sub>2</sub>Ti(CCSiMe<sub>3</sub>)<sub>2</sub>]Cu(η<sup>1</sup>-Mes)(Mes = C<sub>6</sub>H<sub>2</sub>Me<sub>3</sub>-2,4,6)

Maurits D. Janssen, Mathias Herres, Anthony L. Spek, David M. Grove, Heinrich Lang, Gerard van Koten

Journal of the Chemical Society Chemical Communications · 1995 · 32 citations · 17 references

DOIFull text

Open access

Concepts

Abstract

Polynuclear mesitylcopper and mesitylsilver react with [(η5-C5H4SiMes3)2Ti(CCSiMe3)2]1 to afford the monomeric complexes [1·Cu(η1-Mes)]2, and [1·Ag(η1-Mes)]3, in which both alkyne moieties of the 3-titanopenta-1,4-diyne unit are η2-coordinated to a MesCu(Ag) unit.

References

17

Early-late heterobimetallics

Douglas W. Stephan · Coordination Chemistry Reviews · 1989 · 440 citations

Polynuclear aryl derivatives of Group 11 metals. Synthesis, solid state-solution structural relationship, and reactivity with phosphines

Édouard Marc Meyer, Sandro Gambarotta, Carlo Floriani et al. · Organometallics · 1989 · 258 citations

, , +7

Synthesis and characterization of monomeric bis(.eta.2-alkyne)silver(I) compounds: crystal structure of {(.eta.5-C5H4SiMe3)2Ti(C.tplbond.CSiMe3)2}AgNO2

Heinrich Lang, Mathias Herres, László Zsolnai · Organometallics · 1993 · 78 citations

, , +10

Synthesis of Cp2Ti[C.tplbond.CSi(CH3)3]2 and the synthesis and molecular structure of [Cp2TiC.tplbond.CSi(CH3)3]2

Gary L. Wood, Carolyn B. Knobler, M. Frederick Hawthorne · Inorganic Chemistry · 1989 · 73 citations

, , +7

Synthese und Reaktivität von Alkinyl-substituierten Titanocen-Komplexen / Synthesis and Reactivity of Alkyne Substituted Titanocene Complexes

Heinrich Lang, Dietmar Seyferth · Zeitschrift für Naturforschung B · 1990 · 70 citations · Full text

, , +11