Publication | Closed Access
Some evidence against the existence of the liquid‐liquid transition. III. The evaluation of the <i>T</i><sub>ll</sub> event by differential scanning calorimetry
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Citations
31
References
1982
Year
EngineeringDifferential Scanning CalorimetryLiquid-liquid FlowExperimental ThermodynamicsChemistryT Ll TransitionVolatile ComponentsMolecular ThermodynamicsT Ll EventPolymer ProcessingThermodynamicsPolymer ChemistryLiquid‐liquid TransitionPhysicsPhysical ChemistryCalorimetric MethodNatural SciencesPolymer ScienceApplied PhysicsPolymer CharacterizationChemical Kinetics
Abstract The liquid‐liquid transition T ll has been examined by using differential scanning calorimetry as the tool of measurement. The results presented show that for the case of polystyrene, the T ll event appears to be an artifact caused by the presence of volatile components. Purified samples of polystyrene, polydienes, and poly(1‐butene) do not show the T ll transition.
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