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Energetics of the electron‐impact fragmentation of alkoxybenzenes and alkylthiobenzenes
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Citations
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References
1968
Year
EngineeringOrganic ChemistryDetermined HeatsChemistryHeterocycle ChemistryTautomeric Molecular IonsOrganometallic CatalysisMolecular KineticsBiochemistryElectron‐impact FragmentationKetonic StructuresRadical (Chemistry)Quantum ChemistryMolecular ChemistrySupramolecular ChemistryNatural SciencesMain Group ChemistryChemical KineticsMolecular Fragmentation
Abstract Using energetic considerations, ketonic structures are postulated for the [Molefin] + fragments derived from alkoxybenzenes, alkylthiobenzenes and 9‐ethoxyanthracene. Experimentally determined heats of formation for the tautomeric molecular ions derived from anthrone and 9‐anthrol differ by 37 Kcal. mole −1 .
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