Concepedia

Trapping of Trifluoromethyl Radical with Enolacetate and in situ Generated Enol

Kenji Uneyama, Kunimasa Ueda

Chemistry Letters · 1988 · 18 citations · 3 references

DOI

Concepts

Abstract

Abstract Electrochemically generated trifluoromethyl radical can be trapped with enolacetates and enol generated in situ from β-ketoesters and 1,3-diketones, affording trifluoromethylated active methylene compounds.

References

3

Synthesis and Reactivity of <i>N</i>-Trifluoromethyl-<i>N</i>-nitrosotrifluoromethanesulfonamide as a New Type of Trifluoromethylating Agent

Teruo Umemoto, Akira Ando · Bulletin of the Chemical Society of Japan · 1986 · 70 citations

, , +8

Electron-transfer reactions between perfluoroacyl peroxides and methoxybenzenes

Cheng‐Xue Zhao, Gamil M. El‐Taliawi, Cheves Walling · The Journal of Organic Chemistry · 1983 · 47 citations

, , +7

Electrochemical oxidation of trifluoroacetic acid anion.IV. Synthesis and stereochemistry of products of trifluoromethyl radical addition to some mono- and disubstituted olefins

Roger N. Renaud, Philippe Champagne, Marc E. Savard · Canadian Journal of Chemistry · 1979 · 40 citations

, , +7