Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 37 citations · 0 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryOrganic ChemistryCoordination ChemistryInorganic SpectroscopyLigand BindingMagnetism Of Inorganic CompoundsMetal-ligand BondingTransition Metal ComplexesCoordination Compound MagnetismDiamagnetic ComplexesElectronic Spectra Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesMetal-ligand Bonding AnalysisPowder X-ray DiffractionSpectroscopic Characterization Of Metal-ligand BondsSupramolecular Coordination Complexes
Nickel(II) complexes containing 2, 3, 4, or 6 molecules of o-phenylenediamine and some new complexes of 4-methyl-o-phenylenediamine with 3, 4, or 6 diamines present have been characterised by magnetic, infrared, and electronic spectral, thermal analysis, and X-ray powder photograph measurements. The complexes with either 2 or 3 ligand molecules contain bidentate diamine, the 4 : 1 complexes appear to contain both uni- and bi-dentate diamine, whilst only unidentate diamine appears to be present in the 6 : 1 complexes. Criteria for the detection of unidentate diamine based on CN and NH infrared stretching bands are discussed.