Nanocrystalline Rutile TiO[sub 2] Electrode for High-Capacity and High-Rate Lithium Storage

Abstract

A remarkably high lithium storage capability, high rate performance, and cyclability were observed in nanometer-sized rutile electrode at room temperature. The Li insertion ratio, , can be well above 1 in rutile nano-electrode at the first discharge cycled at , and about 0.6–0.7 Li can be reversibly cycled. After the discharge capacities of an ultrafine rutile electrode are still of 132 and when being cycled at 5 and , respectively. Our results suggest that nanometer-sized rutile can be a promising anode material for lithium-ion batteries, especially for high power and high energy density use.