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Crystal Structures of CH<sub>2</sub> = CHCH<sub>2</sub>OC(O)CH<sub>2</sub>CH<sub>2</sub>SnCl<sub>3</sub>.OPPh<sub>3</sub> and BuOC(O)CH(CH<sub>3</sub>)CH<sub>2</sub>SnCl<sub>3</sub>.OPPh<sub>3</sub>
16
Citations
7
References
1993
Year
Materials ScienceInorganic ChemistryCrystal StructureEngineeringBiochemistryNatural SciencesSncl 3O AtomsStructure ElucidationCrystal StructuresMain Group ChemistryChemistryO AtomCrystallographyCrystal Structure DesignInorganic Compound
Abstract The crystal structures of the title compounds, CH 2 CHCH 2 OC(O)CH 2 CH 2 SnCl 3 .OPPh 3 1 and BuOC(O)CH(CH 3 )CH 2 SnCl 3 .OPPh 3 2 , have been determined. The Sn atom in each structure exists in a distorted octahedral geometry defined by three CI atoms, the C and O atoms of a chelating alkoxycarbonylalkyl group and an O atom derived from the strongly attached OPPh 3 ligand.
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