Advanced Synthesis & Catalysis · 2008 · 101 citations · 48 references
Natural SciencesChemical EngineeringChemistryCatalysisInorganic ChemistrySolid-state ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsNanocatalysisSupported CatalystsHeterogeneous Catalyst SynthesisMetal Oxide CatalystsNanostructured CatalystsNitro CompoundsNitro ReductionPalladium CatalystsSelective SynthesisSupported Metal Catalysts
Abstract An efficient, mild and selective synthesis of aromatic and aliphatic amines from the corresponding nitro compounds has been realized by using a ligand‐free heterogeneous nanocrystalline magnesium oxide‐stabilized palladium(0) catalyst, employing molecular hydrogen as the reductant. The catalyst is recovered quantitatively by simple filtration and was reused for several cycles with consistent activity.
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Suchada Utamapanya, Kenneth J. Klabunde, John R. Schlup · Chemistry of Materials · 1991 · 343 citations
Ryan M. Richards, Weifeng Li, Shawn Decker et al. · Journal of the American Chemical Society · 2000 · 249 citations
Natural Sciences, Materials Engineering, Materials Science +17