Perturbation theory for atomic systems

Abstract

Abstract The equations of the Hartree and Hartree-Fock formulations for a perturbed atomic system are discussed. It is pointed out that there are two alternative procedures, one of which is correct to first order in the error of the unperturbed wave function, but not the other, and explicit expressions are written down for the error in the derived perturbed energies in the two cases. A quantitative assessment of the accuracy of the two procedures is provided by the calculation of the dipole and quadrupole polarizabilities of helium, a variation-iteration method being used to solve the relevant equations.