Selective Fluoroalkylation of Cyclopentadienyl and Ethylene Ligands in Reactions of Perfluoroalkyl Iodides with Low-Valent Complexes of Molybdenum and Tungsten: Evidence for a Fluorocarbanion Mechanism

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTSelective Fluoroalkylation of Cyclopentadienyl and Ethylene Ligands in Reactions of Perfluoroalkyl Iodides with Low-Valent Complexes of Molybdenum and Tungsten: Evidence for a Fluorocarbanion MechanismRussell P. Hughes, Susan M. Maddock, Arnold L. Rheingold, and Louise M. Liable-SandsView Author Information Department of Chemistry, 6128 Burke Laboratory Dartmouth College, Hanover, New Hampshire 03755 Department of Chemistry, University of Delaware Newark, Delaware 19716 Cite this: J. Am. Chem. Soc. 1997, 119, 25, 5988–5989Publication Date (Web):June 25, 1997Publication History Received11 February 1997Published online25 June 1997Published inissue 1 June 1997https://pubs.acs.org/doi/10.1021/ja970452khttps://doi.org/10.1021/ja970452krapid-communicationACS PublicationsCopyright © 1997 American Chemical SocietyRequest reuse permissionsArticle Views195Altmetric-Citations14LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Alkyls,Anions,Hydrocarbons,Ligands,Metals Get e-Alerts