A 3D organopolymolybdate polymer with unusual topology functionalized by 1,4-bis(1,2,4-triazol-1-yl)butane through Mo–N bond

Abstract

An unusual (4,6,6)-connected high dimensional organopolymolybdate polymer by 1,4-bis(1,2,4-triazol-1-yl)butane coordinating directly to a molybdenum atom has been obtained under hydrothermal condition, which exhibits a self-penetrating framework with (44·5·6)(45·54·66)(48·52·65) topology assembled from 2D self-threading skeleton.