Extraction of radioactive cesium using innovative functionalized porous materials

Abstract

A new approach to an efficient and selective extraction of Cs+ ions from water, sea water enriched with Cs+ and a radioactive solution simulating the effluents of the Fukushima reactors (137Cs, 29 kBq L−1) was developed by using porous silica- or glass-based nanocomposites containing Prussian blue type nanoparticles, Co2+/[Fe(CN)6]3−, with sizes below 10 nm. A particular emphasis is given on the kinetics of cesium sorption fitted by using the classical reaction order model as well as a diffusion model in order to better understand the sorption mechanism. Compared to the amount of Co2+/[Fe(CN)6]3− nanoparticles, the sorption capacities of studied nanocomposites are more than three times higher than the ones observed for the respective bulk materials. These nanocomposites present a high selectivity to Cs+ and extract it in trace amounts.