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An unusual route to the isopolymolybdates; Octamolybdate β-[Mo8O26]4− and hexamolybdate [Mo6O19]2−. Reaction of dioxomolybdenum complexes with triphenylphosphonium ylides. Crystal structures of the salts [PPh3CH2COOEt]+2[NH2Et]+2 [Mo8O26]4−, [PPh3CH2COOEt]+2 [Mo6O19]2−, and [PPh3CH2Ph]+2 [Mo6O19]2−

Inorganic CompoundInorganic ChemistryBiochemistryNatural SciencesCoordination ComplexUnusual RouteMolecular ComplexChemistryTriphenylphosphonium YlidesInorganic SynthesisDioxomolybdenum Complexes