Glasslike Heat Conduction in High-Mobility Crystalline Semiconductors

Abstract

The thermal conductivity of polycrystalline semiconductors with type-I clathrate hydrate crystal structure is reported. Ge clathrates (doped with Sr and/or Eu) exhibit lattice thermal conductivities typical of amorphous materials. Remarkably, this behavior occurs in spite of the well-defined crystalline structure and relatively high electron mobility ( $\ensuremath{\sim}100{\mathrm{cm}}^{2}/\mathrm{V}\mathrm{s}$). The dynamics of dopant ions and their interaction with the polyhedral cages of the structure are a likely source of the strong phonon scattering.