Concepedia

Cyclohexane selective oxidation over metal–organic frameworks of MIL-101 family: superior catalytic activity and selectivity

Nataliya V. Maksimchuk, Konstantin A. Kovalenko, Vladimir P. Fedin, Oxana A. Kholdeeva

Chemical Communications · 2012 · 198 citations · 33 references

DOI

Concepts

Abstract

Mesoporous metal-organic frameworks Cr- and Fe-MIL-101 are highly efficient, true heterogeneous and recyclable catalysts for solvent-free selective oxidation of cyclohexane with molecular oxygen and/or tert-butyl hydroperoxide under mild conditions.

References

33

Functional Porous Coordination Polymers

Susumu Kitagawa, Ryo Kitaura, Shin‐ichiro Noro · Angewandte Chemie International Edition · 2004 · 11K citations

, , +17

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

Gérard Férey, Caroline Mellot‐Draznieks, Christian Serre et al. · Science · 2005 · 5.3K citations · Full text

, , +16

Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery

K. Taylor-Pashow, Joseph Della Rocca, Zhigang Xie et al. · Journal of the American Chemical Society · 2009 · 1.5K citations · Full text

, , +17

Cyclohexane oxidation continues to be a challenge

Ulf Schuchardt, Dilson Cardoso, Ricardo Sercheli et al. · Applied Catalysis A General · 2001 · 676 citations · Full text

, , +9

Zeolite-<i>like</i> Metal−Organic Frameworks as Platforms for Applications: On Metalloporphyrin-Based Catalysts

Mohamed H. Alkordi, Yunling Liu, Randy W. Larsen et al. · Journal of the American Chemical Society · 2008 · 603 citations

, , +17