Macromolecules · 2001 · 19 citations · 25 references
Natural SciencesChemistryMaterials SciencePolymer ChemistryPolymer MaterialsSpectroscopic AnalysisPolymer AnalysisPolymer CharacterizationPolymer PhysicsPolymer SimulationPolymer StructureRaman SpectroscopyPolymer TacticityPolypropyleneQuantitative DeterminationRaman Data AnalysisRaman ScatteringRaman SpectraStereoregularityTacticity
Raman spectra of syndiotactic polypropylenes of different stereoregularity are reported. Spectra for ordered and disordered structures of these polymers were simulated using a small number of parameters. The features that occur in the 300 and 400 cm -1 regions can be used to assess chain tacticity. A quantitative determination of the racemic content of polypropylene can be obtained from the Raman spectrum in the range of tacticity studied.
25
Vibrational analysis of peptides, polypeptides, and proteins. I. Polyglycine I
W. H. Moore, S. Krimm · Biopolymers · 1976 · 179 citations · Full text