Publication | Closed Access
The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis
152
Citations
10
References
2004
Year
EngineeringInorganic PhotochemistryPhotosynthetic WaterChemistryRedox BiologyInorganic CompoundChemical EngineeringBioenergeticsPhotocatalysisRedox ChemistryPhotosynthesisHealth SciencesMaterials ScienceInorganic ChemistryPhotochemistryPhotosystemsMechanistic PhotochemistrySynthetic EntryCatalysisInorganic SynthesisCluster Chemistry
Synthetic entry has been achieved into high oxidation state Mn-Ca cluster chemistry with the preparation of [Mn(13)Ca(2)O(10)(OH)(2)(OMe)(2)(O(2)CPh)(18)(H(2)O)(4)]; the structure contains [Mn(4)CaO(4)] sub-units similar to that found in the photosynthetic water oxidizing complex.
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