Crystal Fields and the Effective-Point-Charge Model in the Rare-Earth Pnictides

Abstract

Neutron scattering and specific-heat studies of the crystal fields in the rare-earth monophosphides are reported. It is found that the fourth-order crystal-field parameters for the phosphides and for other rare-earth pnictides fall on a universal curve which is close to that predicted by an effective-point-charge model for the light rare earths but deviates markedly for the heavy rare earths.