Angewandte Chemie International Edition · 2011 · 174 citations · 23 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials ChemistrySurface ScienceCatalytic MaterialsCrystal ChemistryCrystal EngineeringPhotocatalysisPhotochemical SynthesisPhotochemistryCrystal FacetsGas Phase OxidationPhotocatalyst PreparationPhotocatalytic MaterialsPhotocatalytic OxidationPhotocatalytic Water TreatmentTitanium Dioxide PhotocatalysisTitanium Oxides
Put your best face forward: The performance of TiO2 anatase crystals in energy and environmental applications is normally correlated with the TiO2 crystal facets exposed, and increasing the percentage of highly reactive surfaces is extremely important. A new gas-phase oxidation process using TiCl4 as precursor now yields anatase TiO2 single crystals with primarily high-index {105} facets, which can cleave water photocatalytically. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Electrochemical Photolysis of Water at a Semiconductor Electrode
Akira Fujishima, Kenichi Honda · Nature · 1972 · 33.7K citations
Michaël Grätzel · Nature · 2001 · 12.6K citations · Full text
Anatase TiO2 single crystals with a large percentage of reactive facets
Hua Gui Yang, Chenghua Sun, Shi‐Zhang Qiao et al. · Nature · 2008 · 4.1K citations
Natural Sciences, Materials Engineering, Materials Science +16