Concepedia

Novel Networks of Unusually Coordinated Silver(<scp>I</scp>) Cations: The Wafer‐Like Structure of [Ag(pyz)<sub>2</sub>][Ag<sub>2</sub>(pyz)<sub>5</sub>](PF<sub>6</sub>)<sub>3</sub>·2G and the Simple Cubic Frame of [Ag(pyz)<sub>3</sub>](SbF<sub>6</sub>)

Lucia Carlucci, Gíanfranco Ciani, Davide Μ. Proserpio, Angelo Sironi

Angewandte Chemie International Edition in English · 1995 · 286 citations · 20 references

DOI

Concepts

Abstract

The silver salts AgPF6 and AgSbF6 react with pyrazine to give unprecedented networks of two- and three-dimensional cubic units. The PF derivative has a layered structure, whereas the SbF derivative (shown schematically on the right) contains a simple cubic frame of the α-polonium type.

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