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Practical and Efficient 1α-Hydroxylation of 4,4-Dimethyl-2-Ene Derivatives in Terpenic Series
16
Citations
31
References
1997
Year
EngineeringOrganic ChemistryChemistryChemical DerivativeBiosynthesisNatural Product BiosynthesisStereoselective Synthesis1α-Hydroxy CompoundsDerivativesBiochemistryDiversity-oriented SynthesisTriptycal SynthesisTerpenic SeriesNatural Product SynthesisEnantioselective SynthesisBiomolecular EngineeringNatural SciencesSeo2/pyridine N-oxideSynthetic Chemistry
Abstract The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO2/pyridine N-oxide, is described.
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