Concepedia

Crystal Structure of a Tris(dithiolene) Vanadium(IV) Complex Having Unprecedented <i>D</i>3<i>h</i> Symmetry

Mitsuru Kondo, Seika Minakoshi, Kazuko Iwata, Toshio Shimizu, Hiroyuki Matsuzaka, Nobumasa Kamigata, Susumu Kitagawa

Chemistry Letters · 1996 · 34 citations · 6 references

DOI

Concepts

Abstract

Abstract The crystal structure of a tris(dithiolene)vanadium(IV) complex, [V(S2C2H2)3] (1), was determined. This complex shows the first instance of the nearly perfect D3h geometry in tris(dithiolene) vanadium(IV) complexes. In comparison with 1, the crystal structures of (NEt4)2[V(bdt)3] (bdt2− = 1,2-benzenedithiolate) (2) and (NEt4)2[V(tdt)3] (tdt2− = 3,4-toluenedithiolate) (3) having distorted Oh geometries were also determined by X-ray crystallography.

References

6

Synthetic, structural, and physical studies of bis(triethylammonium) tris(catecholato)vanadate(IV), potassium bis(catecholato)oxovanadate(IV), and potassium tris(catecholato)vanadate (III)

Stephen R. Cooper, Yun Bai Koh, Kenneth N. Raymond · Journal of the American Chemical Society · 1982 · 207 citations

, , +9

Coordination Compounds with Delocalized Ground States. Bisdithioglyoxalnickel and Related Complexes<sup>1a,b</sup>

G. N. Schrauzer, V. P. Mayweg · Journal of the American Chemical Society · 1965 · 153 citations

, , +8

Trigonal-prismatic coordination. Crystal and molecular structure of tris (cis-1,2-diphenylethylene-1,2-dithiolato)vanadium

Richard Eisenberg, Harry B. Gray · Inorganic Chemistry · 1967 · 68 citations

, , +11

Conductive molecular crystals from three-dimensional building blocks: synthesis and characterization of tris(bis(ethylenedithio)tetrathiafulvalenium) bis(tris(2-thioxo-1,3-dithiole-4,5-dithiolato)vanadate), [ET]3[V(dmit)3]2, and the corresponding tetramethyltetraselenafulvalenium salt

William E. Broderick, Ellen M. McGhee, Martin R. Godfrey et al. · Inorganic Chemistry · 1989 · 59 citations

, , +15

Trigonal-prismatic vs. octahedral coordination in a series of tris(benzene-1,2-dithiolato) complexes. 3. Crystal and molecular structure of bis(tetramethylammonium) tris(benzene-1,2-dithiolato) zirconate(IV), [CH3)4N]2[Zr(S2C6H4)3]

Martín Cowie, Michael J. Bennett · Inorganic Chemistry · 1976 · 52 citations

, , +16