Concepedia

A new reaction of arylphospholes: site-selective phosphorylation through reaction with phosphorus tribromide

György Keglevich, Tungalag Chuluunbaatar, András Dobó, László Tke

Journal of the Chemical Society Perkin Transactions 1 · 2000 · 15 citations · 6 references

DOI

Concepts

Abstract

The reaction of arylphospholes 1a–c with phosphorus tribromide followed by treatment with morpholine afforded the 2- or 3-substituted species 3a,b or 7 (which after oxidation gave 4a,b or 8) in a selective manner.

References

6

1-(2,4,6-Tri-<i>tert</i>-butylphenyl)-3-methylphosphole:  A Phosphole with a Significantly Flattened Phosphorus Pyramid Having Pronounced Characteristics of Aromaticity

György Keglevich, Zsolt Böcskei, György M. Keserű et al. · Journal of the American Chemical Society · 1997 · 95 citations

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Phospholes with reduced pyramidal character from steric crowding III NMR and X-ray diffraction studies on 1-(2,4,6-tri-isopropylphenyl)-3-methylphosphole

György Keglevich, Louis D. Quin, Zsolt Böcskei et al. · Journal of Organometallic Chemistry · 1997 · 46 citations

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Study of the planarization of the tricordinate phosphorus in phospholes; photoelectron spectra and structure of partially planarized phospholes

László Nyulászi, László Soós, György Keglevich · Journal of Organometallic Chemistry · 1998 · 37 citations

, , +7

Platinum Complexes of Phospholes with Reduced Pyramidal Character from Steric Crowding

Zsolt Csók, György Keglevich, György Petőcz et al. · Inorganic Chemistry · 1999 · 30 citations

, , +7

C-phosphorylation of n-methylpyrrole

Sergey P. Ivonin, Tetjana E. Terikovska, A. A. Chaikovskaya et al. · Heteroatom Chemistry · 1999 · 18 citations

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